Absolute Configuration and Enantioselective Synthesis of Spiculisporic Acid.
نویسندگان
چکیده
منابع مشابه
Enantioselective total synthesis of colomitides and their absolute configuration determination and structural revision.
An efficient stereoselective synthetic approach to colomitides, 2,7-dioxabicyclo[3.2.1]octane-type natural products, is reported. Key steps are a stereocontrolled aldol reaction and a gold-catalyzed cycloisomerization. This synthetic strategy has been applied for the first asymmetric total synthesis of the proposed colomitides and their possible diastereomers. Comparison of their 1H and 13C NMR...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1984
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.38b-0837